Skip to main content
Article
Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters
Synthetic Communications
  • Nathaniel Ivan, University of Dayton
  • Vladimir Benin, University of Dayton
  • Alexander Morgan, University of Dayton
Document Type
Article
Publication Date
1-1-2013
Abstract

The current article reports in detail the preparation of two phosphonoterephthalic acids: 2-phosphonoterephthalic acid (1) and 2,5-diphosphonoterephthalic acid (2). Efficient, scalable syntheses have been developed for both compounds based on Pd-catalyzed coupling reactions of iodinated terephthalate esters. Phosphonoterephthalic acids are potentially useful as flame-retardant additives or as monomers for the construction of acid-pendant polymer chains.

Inclusive pages
1831-1836
ISBN/ISSN
0039-7911
Document Version
Postprint
Comments

The document available for download is the authors' accepted manuscript, posted here in compliance with the publisher's policy on self-archiving. Some differences may exist between this version and the publisher's version; as such, researchers wishing to quote directly from it are advised to consult the version of record, available at many libraries or from the publisher: http://0-dx.doi.org.library.simmons.edu/10.1080/00397911.2012.673448

Permission documentation is on file.

Publisher
Taylor & Francis
Peer Reviewed
Yes
Citation Information
Nathaniel Ivan, Vladimir Benin and Alexander Morgan. "Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters" Synthetic Communications Vol. 43 Iss. 13 (2013)
Available at: http://0-works.bepress.com.library.simmons.edu/vladimir_benin/11/