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Article
Preparation and Characterization of Some Substituted Benzyl N-nitrosocarbamates Containing an N-2-(methylthio)ethyl or a Bis(2-aminoethyl)sulfide Functionality
Synthetic Communications
  • Satya Venkata, University of Dayton
  • Eric Shamo, University of Dayton
  • Vladimir Benin, University of Dayton
Document Type
Article
Publication Date
1-1-2009
Abstract

The synthesis and characterization of some substituted benzyl N-nitrosocarbamates with an N-2-(methylthio)ethyl or a bis(2-aminoethyl)sulfide functionality is reported, as a part of a long-term goal to design and prepare novel photolabile structures that could be used as substances for controlled release of alkylating and/or crosslinking agents. The synthesis was accomplished by reaction of benzyl chloroformates with the corresponding amines, resulting in the preparation of carbamates. The latter were subsequently nitrosated, utilizing two different N-nitrosation methods, to yield the target structures.

Inclusive pages
1406–1414
ISBN/ISSN
0039-7911
Document Version
Postprint
Comments

The document available for download is the authors' accepted manuscript, posted here in compliance with the publisher's policy on self-archiving.

Some differences may exist between this version and the publisher's version; as such, researchers wishing to quote directly from it are advised to consult the version of record, available at many libraries or from the publisher.

Permission documentation is on file.

Publisher
Taylor & Francis
Peer Reviewed
Yes
Citation Information
Satya Venkata, Eric Shamo and Vladimir Benin. "Preparation and Characterization of Some Substituted Benzyl N-nitrosocarbamates Containing an N-2-(methylthio)ethyl or a Bis(2-aminoethyl)sulfide Functionality" Synthetic Communications Vol. 39 Iss. 8 (2009)
Available at: http://0-works.bepress.com.library.simmons.edu/vladimir_benin/15/